研究队伍
姓名: 王来来 性别:
学科类别: 物理化学 职务: 课题组长
学历: 博士 职称: 研究员
电话: 0931-4968161 传真: 0931-4968129
电子邮件: wll@licp.cas.cn
通讯地址: 甘肃省兰州市城关区天水中路18号

简  历:

  王来来,研究员,博导。1987年本科毕业于西北师范大学化学系,1990年兰州大学硕士研究生毕业,获理学硕士学位.1990年进入中科院兰化所,1994~1997年中科院兰化所在职博士研究生,获理学博士学位。2001~2003年在香港理工大学应用生物和化学科技学系从事手性膦配体合成和不对称羰化反应研究;2006.11~2007.2在香港理工大学进行合作研究,从事α-烯烃与CO的不对称交替共聚反应研究。

研究方向:

不对称催化

获奖及荣誉:

  甘肃省科技进步二等奖:不对称催化羰化和氢化反应研究(1999年)

承担科研项目:

  (1)负责承担国家自然科学基金委面上项目:

  不对称羰化合成手性功能高分子聚酮(2005.01-2007.12),

  不对称酰胺羰化合成手性N-酰基-α-氨基酸(2008.01-2010.12),

  α-烯烃不对称三羰基化反应研究(2011.1-2013.12),

  木质素的接枝共聚反应研究(2012.01-2015.12)。

  (2)负责承担国家自然科学基金委化学部主任专项基金:

  离子液体中的对映选择性交替共聚反应(2004.01-2004.12),

  钯催化的不对称酰胺羰化反应研究(2007.01-2007.12)。

  (3)负责承担中科院知识创新工程重要方向项目:

  “离子液体应用研究(No.KGXCX2-SW-211)”子课题“离子液体中的不对称催化反应研究”(2004.01-2006.12)。

  (4)负责承担甘肃省科技支撑计划-社会发展计划项目:

  造纸废液中木质素用于化学固沙剂的制备研究( 2007.07-2009.07)。

  (5)负责承担中科院“西部之光”人才培养计划资助项目:

  造纸废液中木质素用于化学固沙剂的制备研究(2009.12-2012.12)。

  (6)负责承担与江苏理文化工有限公司合作项目:

  用于生产偏氟乙烯催化剂的制备及性能研究(2014.01-2016.12)。

  (7)参加国家自然科学基金重点项目:

  均相络合催化的应用基础研究(2000.01-2003.12)。

代表论著:

  近期发表的代表性论文:

  (1) P. Y. Choy, L. L. Wang* and F. Y. Kwong*,Regioselective direct C-3 arylation of imidazo[1,2-α]pyridines with aryl tosylates and mesylates promoted by palladium-phosphine complexes,The Journal of Organic Chemistry, 2015, 80, 1457。

  (2) H. F. Li, Z. B. Pang, P. Gao and L. L. Wang*, Fe(III)-catalyzed grafting copolymerization of lignin with styrene and methyl methacrylate through AGET ATRP using triphenyl phosphine as ligand, RSC Adv., 2015, 5, 54387.

  (3) A. P. Xing, L.L. Wang*,Efficient novel 1, 2-diphosphite ligands derived from D-mannitol in the Pd-catalyzed asymmetric allylic alkylation. Tetrahedron 2014, 70, 8822.

  (4) A. P. Xing, C. B. Bai , L. L. Wang*, Chiral phosphite ligands derived from L-(+)-tartaric acid: synthesis and application in the Cu-catalyzed 1,4-conjugate addition of organozincs to cyclic enones, Tetrahedron, 2013, 69, 455.

  (5) Q. L. Zhao, X, Miao, L. L. Wang*, Enantioselective hydrogenation of functionalized olefins catalyzed by using Rh-chiral bidentatephosphite ligand complexes, Tetrahedron: Asymmetry, 2013, 24, 104.

  (6) Q. L. Zhao, L. L. Wang *, Synthesis of novel chiral bidentatephosphite ligands derived from pyranoside backbone of monosaccharides and their application in Cu-Catalyzed conjugate addition of dialkylzinc to enones , Tetrahedron: Asymmetry,2011, 22, 1885.

  (7) Q. L. Zhao, L. L. Wang *, A. P. Xing. Synthesis of novel diphosphite ligands derived from D-mannitol and their application in Cu-catalyzed enantio-selective conjugate addition of organozinc to enones. Tetrahedron: Asymmetry, 2010, 21(24), 2993.

  (8) Q. L. Zhao, M. K. Tse, L. L. Wang*. Synthesis of diphosphite ligands derived from glucopyranoside and their application in Cu-catalyzed asymmetric 1,4-addition of organozinc to enones. Tetrahedron: Asymmetry, 2010, 21(23), 2788.

  (9) Y. M. Cui, L. L. Wang,* et. al.,“A highly efficient chiral-bridged diphosphine ligand modified cationic Palladium (II) catalyst system for asymmetric alternating copolymerization of propene and carbon monoxide”, Synlett, 2009 (16), 2696.

  (10) Q. L. Zhao, M. Yang, L. L. Wang,* “Efficient ligand-free, palladium catalyzed amidocarbonylation in ionic liquids: facile synthesis of N-acyl-a-arylglycines”, Synthetic Communications, 2008, 38, 4460.

  (11) Q. L. Zhao, L. L. Wang,* Albert S. C. Chan, “Cu-catalyzed enantioselective conjugate addition of diethyzinc to cyclic enones with chiral phosphite ligands derived from 1,2:5,6-di-O-cyclohexylidene-D-mannitol”, Tetrahedron: Asymmetry, 2007, 18, 1899.

  (12) H. J. Wang, L. L. Wang,* Albert S. C. Chan,“Pd-catalyzed asymmetric alternating copolymerization of propene with carbon monoxide using ionic liquids”, Tetrahedron: Asymmetry, 2006,17, 7.

  (13) L. L. Wang, R. W. Guo, Albert S. C. Chan,“Rhodium catalyzed asymmetric hydroformylation of vinylarenes with novel chiral P,N-ligands derived from 1,2:5,6-di-O-cyclohexylidene-D-mannitool”, Tetrahedron: Asymmetry, 2005, 16, 3198.

  (14) L. L. Wang, Z. Y. Zhou, Albert S. C. Chan, “Synthesis of new chiral aryl diphosphite ligands derived from pyranoside backbone of monosacharides and their application in copper-catalyzed asymmetric conjugate addition of diethylzinc to cyclic enones”, Adv. Synth. Catal., 2004, 346, 947.

  (15) L. L. Wang, Albert S. C. Chan, X. L. Hou, and L. X. Dai, “Asymmetric hydroesterification of styrene using catalysts with planar-chiral ferrocene oxazoline ligands”, Tetrahedron: Asymmetry, 2003, 14, 2291.

  获得授权的国家发明专利:

  (1) 王来来,王海君,不对称羰化法合成手性功能高分子聚酮的方法,专利号:ZL200510048322.4.

  (2) 王来来,李成,酰胺羰化反应合成N-酰基苯基甘氨酸的方法,专利号: ZL200610104993.2.

  (3) 王来来,赵庆鲁,酰胺羰化反应合成N-乙酰基-α-苯基甘氨酸的方法,专利号:ZL200810150288.5.

  (4) 王来来,赵庆鲁,甘露醇衍生的手性双齿亚磷酸酯配体及其制备方法与用途,专利号:ZL201010551598.5.

  (5) 王来来,赵水侠,屈建军,一种化学固沙剂,专利号:ZL200910117687.6.

  (6) 王来来,董治宝,赵水侠,一种高分子材料化学固沙剂的制备方法,专利号:ZL200810150285.1.

  (7) 王来来,董治宝,赵水侠,木质素磺酸盐接枝共聚物化学固沙剂制备方法,专利号:ZL200710188572.7.

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