姓名: | 王培学 | 性别: | 男 |
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学科类别: | 职务: | ||
学历: | 博士 | 职称: | 副研究员 |
电话: | 17664086809 | 传真: | |
电子邮件: | peixuew@licp.cas.cn | ||
通讯地址: | 甘肃省兰州市天水中路18号 |
简 历:
王培学,博士,中国科学院兰州化学物理研究所副研究员。
2006年9月至2010年7月, 山东师范大学, 应用化学, 学士
2010年9月至2015年12月, 中国科学院兰州化学物理研究所, 物理化学, 博士, 导师: 邓友全
2016年1月至2021年8月, 中国科学院兰州化学物理研究所, 羰基合成与选择氧化国家重点实验室, 助理研究员
2021年9月至今, 中国科学院兰州化学物理研究所, 羰基合成与选择氧化国家重点实验室, 副研究员
研究方向:
1.二氧化碳催化转化
2.绿色合成氨基甲酸酯
3.碳酸二烷基酯及异氰酸酯
获奖及荣誉:
承担科研项目:
1.二氧化碳制碳酸甲乙酯关键技术研发, 参与, 境内委托项目, 2023-06--2025-06
2.新型有机硅多异氰酸酯固化剂及其功能涂层, 负责人, 研究所自主部署, 2022-01--2023-12
3.基于碳酸乙烯酯固载化催化剂的小试反应开发, 参与, 境内委托项目, 2021-07--2022-07
4.离子液体材料研制, 参与, 境内委托项目, 2021-04--2023-03
5.离子液体功能介质与材料研发与规模生产, 参与, 地方任务, 2020-11--2023-10
6.离子液体材料研制, 参与, 境内委托项目, 2019-10--2022-03
7.纳米金的精细调控及其催化CO2羰基化制N-取代二氨基甲酸烷基酯的性能研究, 负责人, 国家自然科学基金青年科学基金项目, 2019-01--2021-12
8.氨基三氮唑类金属盐催化CO2与二胺合成聚脲, 负责人, 中国科学院“西部青年学者”B类, 2017-01--2019-12
代表论著:
1. Peixue Wang; Shimin Liu; Xinjiang Cui*; Yang Wu; Feng Shi*, Effective synthesis of diethyl carbonate over Mg-Y composite oxides via alcoholysis of ethyl carbamate, New Journal of Chemistry, 2024, 48, 7489-7496.
2. Peixue Wang; Shimin Liu; Xinjiang Cui; Yang Wu; Feng Shi*, Indirect use of CO2: synthesis of N-substituted dicarbamates via polyurea intermediates over a Zn-based metal azolate framework, Catalysis Science & Technology, 2024, 14, 2286-2293.
3. 刘士民#;王培学#;邓友全*,非光气制异氰酸酯绿色过程,中国科学.化学2020, 50, 235-244.
4. Peixue Wang*; Dawei Zhou; Yuqing Fei; Yan Long; Youquan Deng*, Formation and Depolymerization of Oligomers during Thermal Cracking of Silicon-Containing Carbamates, ChemPlusChem, 2019, 84, 1039-1045.
5. Dawei Zhou; Peixue Wang*; Yan Long; Yuqing Fei; Youquan Deng*; Recovery of the polymers formed during thermal cracking of N-substituted dicarbamates over Fe-Ni/Al2O3, Catalysis Science & Technology, 2019, 9, 2282-2290.
6. Yan Long; Peixue Wang; Yuqing Fei; Dawei Zhou; Shimin Liu*; Youquan Deng*, One-pot synthesis of N-methylpyrrolidine (NMPD) using Cu- and Ni-modified ZSM-5 as an efficient catalyst, Green Chemistry, 2019, 21, 141-148.
7. Peixue Wang; Yuqing Fei; Qinghe Li; Youquan Deng*, Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst, New Journal of Chemistry, 2018, 42, 1202-1207.
8. Peixue Wang; Yuqing Fei; Yan Long; Youquan Deng*, Catalytic polymerization of CO2 to polyureas over K3PO4 catalyst, Journal of CO2 Utilization, 2018, 28, 403-407.
9. Peixue Wang; Shimin Liu; Youquan Deng*, Important Green Chemistry and Catalysis: Non-phosgene Syntheses of Isocyanates-Thermal Cracking Way, Chinese Journal of Chemistry, 2017, 35, 821-835.
10. Peixue Wang; Yuqing Fei; Qinghe Li; Youquan Deng*, Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature, Green Chemistry, 2016, 18, 6681-6686.
11. Qinghe Li; Peixue Wang; Shimin Liu; Yuqing Fei; Youquan Deng*, Catalytic degradation of polyurea: synthesis of N-substituted carbamates with CuO-ZnO as the catalyst, Green Chemistry, 2016, 18, 6091-6098.
12. Peixue Wang; Qinghe Li; Shimin Liu; Deng Youquan*, Converting urea into high value-added 2-oxazolidinones under solvent-free conditions, RSC Advances, 2016, 6, 94382-94386.
13. Peixue Wang#; Xiangyuan Ma#; Qinghe Li; Benqun Yang; Jianpeng Shang; Deng Youquan*, Green synthesis of polyureas from CO2 and diamines with a functional ionic liquid as the catalyst, RSC Advances, 2016, 6, 54013-54019.
14. Peixue Wang; Shimin Liu; Feng Zhou; Benqun Yang; Ahmad S. Alshammari; Deng Youquan*, Catalytic alcoholysis of urea to diethyl carbonate over calcined Mg-Zn-Al hydrotalcite, RSC Advances, 2015, 5, 19534-19540.
15. Peixue Wang; Shimin Liu; Feng Zhou; Benqun Yang; Ahmad S. Alshammari; Youquan Deng*, Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts, RSC Advances, 2015, 5, 84621-84626.
16. Peixue Wang; Shimin Liu; Xiangyuan Ma; Yude He; Ahmad S. Alshammari; Youquan Deng*, Binary Mg-Fe oxide as a highly active and magnetically separable catalyst for the synthesis of ethyl methyl carbonate, RSC Advances, 2015, 5, 25849-25856.
17. Peixue Wang; Yubo Ma; Shimin Liu; Feng Zhou; Benqun Yang; Youquan Deng *, N-Substituted carbamate synthesis using urea as carbonyl source over TiO2-Cr2O3/SiO2 catalyst, Green Chemistry, 2015, 17, 3964-3971.
18. Peixue Wang; Shimin Liu; Liujin Lu; Xiangyuan Ma; Yude He; Youquan Deng*, Separation of dibutyl carbonate/butyl carbamate close-boili ng mixture using imidazolium-based ionic liquids, RSC Advances, 2015, 5, 62110-62115.
19. Peixue Wang; Shimin Liu; Feng Zhou; Benqun Yang; Ahmad S. Alshammari; Liujin Lu, Youquan Deng*, Two-step synthesis of dimethyl carbonate from urea, ethylene glycol and methanol using acid–base bifunctional zinc-yttrium oxides, Fuel Processing Technology, 2014, 126, 359-365.
专利成果:
1. 一种热裂解制异氰酸酯过程中形成聚合物的解聚方法, 发明专利, 2019, 专利授权号: CN109734626A
2. 一种以尿素为羰源合成氮取代二氨基甲酸酯的方法, 发明专利, 2017, 专利公开号: CN106397271A
3. 一种非贵金属催化制备二酰胺的方法, 发明专利, 2016, 专利公开号: CN105949077A
4. 一种离子液体催化CO 2 和二胺制备聚脲的方法, 发明专利, 2016, 专利公开号: CN105860059A
5. 尿素醇解直接合成碳酸二乙酯同时副产氨基甲酸乙酯的方法, 发明专利, 2015, 专利公开号: CN104761454A
6. 一种用于两组分共沸物或近沸点混合物的分离方法, 发明专利, 2015, 专利公开号: CN104761422A
7. 一种酯交换合成碳酸二苯酯的方法, 发明专利, 2014, 专利公开号: CN103664626A
8. 一种苯氨基甲酸酯的清洁合成方法, 发明专利, 2013, 专利公开号: CN103172541A
9. 一种温和条件下氨基甲酸酯的合成方法, 发明专利, 2013, 专利号: CN103172538A
10. 一种快速合成四氟硼酸室温离子液体的方法, 发明专利, 2023, 专利申请号: 202311727207.4
11. 一种热裂解制备硅氧烷二异氰酸酯的方法, 发明专利, 2023, 专利申请号: 202311728077.6
12. 一种负载型固体碱催化剂及其在制备碳酸甲乙酯和碳酸二乙酯中的应用,发明专利, 2024, 专利申请号: 2024105256291
13. 一种钙基固体碱催化剂及其制备与应用,发明专利, 2024, 专利申请号: 2024105254968
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