| 姓名： | 代兴超 | 性别： | 男 |
|---|---|---|---|
| 学科类别： | 催化化学 | 职务： | |
| 学历： | 博士 | 职称： | 副研究员 |
| 电话： | 17693184317 | 传真： | 0931-4968019 |
| 电子邮件： | daixingchao@licp.cas.cn | ||
| 通讯地址： | 甘肃省兰州市城关区天水中路18号 | ||
简 历：
代兴超，男，博士，中国科学院兰州化学物理研究所特聘青年研究员，博士生导师，国家引才计划入选者。2019年博士毕业于中国科学院兰州化学物理研究所物理化学专业，师从石峰研究员。2020.09-2024.07在德国莱布尼茨催化研究所进行博士后研究，合作导师为Angelika Brückner教授。2024年8月入职中国科学院兰州化学物理研究所，主要从事二氧化碳和生物基平台分子的选择性催化转化研究。迄今在Angew. Chem. Int. Ed.、Nat. Commun.等国际著名刊物发表学术论文40多篇，编著英文专著3部，授权中国发明专利3件。
研究方向：
1. 二氧化碳转化
2. 生物质转化
3. 催化胺化
获奖及荣誉：
1. 国家引才计划入选者
2. 甘肃省自然科学一等奖（排名4）
3. 中国科学院院长优秀奖
4. 中国科学院优秀毕业生
承担科研项目：
1. 国家级人才计划项目
2. 国家自然科学基金面上项目
3. 中国科学院先导B类课题
4. 甘肃省科技重大专项子课题
5. 研究所特聘青年研究员人才项目
代表论著：
1. Xingchao Dai* and Jabor Rabeah*. Oxidative N-Formylation of Amines to Formamides,ChemCatChem,2025,17,e202500359.
2. Xingchao Dai*,Yunyan Han,Haijun Jiao*,Angelika Brückner,Feng Shi* and Jabor Rabeah*. Mild oxidative N-formylation of amines with biobased glycolaldehyde over C3N4 supported Cu catalyst under green solvent,Chem. Eng. J.,2025,508,160963.
3. Xingchao Dai,Yunyan Han,Haijun Jiao*,Feng Shi*,Jabor Rabeah* and Angelika Brückner*. Aerobic Oxidative Synthesis of Formamides from Amines and Bioderived Formyl Surrogates,Angew. Chem. Int. Ed.,2024,63,e202402241 (Inside Cover Picture).
4. Xingchao Dai,Teng Li,Bin Wang,Carsten Kreyenschulte,Stephan Bartling,Shujuan Liu,Dongcheng He,Hangkong Yuan,Angelika Brückner,Feng Shi,Jabor Rabeah* and Xinjiang Cui*. Tailoring Active Cu2O/Copper Interface Sites for N-Formylation of Aliphatic Primary Amines with CO2/H2,Angew. Chem. Int. Ed.,2023, 62,e202217380.
5. Liping Zhang,Teng Li,Xingchao Dai (共一),Jian Zhao,Ce Liu,Dongcheng He,Kang Zhao,Peiqing Zhao* and Xinjiang Cui*. Water Activation Triggered by Cu-Co Double-Atom Catalyst for Silane Oxidation,Angew. Chem. Int. Ed.,2023, 135,e202313343.
6. Xingchao Dai*,Xinzhi Wang,Carsten Kreyenschulte,Hangkong Yuan,Angelika Brückner,Feng Shi* and Jabor Rabeah*. Cu-Catalysed sustainable synthesis of formamide with glycerol derivatives as a carbonyl source via a radical-relay mechanism,Green Chem.,2023,25,1464.
7. Yujing Zhang*,Xingchao Dai (共一), Jixue Wang,Junxi Liang,Jabor Rabeah,Xia Tian,Xiaoqiang Yao,Yanbin Wang,and Shaofeng Pang*. In situ generated Cu(I) catalytic system for oxidative N-formylation of N-heterocycles and normal amines with methanol,ChemSusChem,2023,16,e202202104.
8. Jinling Wang,Xingchao Dai (共一),Hualin Wang,Honglai Liu,Jabor Rabeah,Angelika Brückner*,Feng Shi,Ming Gong and Xuejing Yang*. Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst,Nat. Commun.,2021,12:6840.
9. Xingchao Dai,Xinzhi Wang,Jabor Rabeah,Carsten Kreyenshulte,Angelika Brückner*,and Feng Shi*. Supported CuII Single-Ion Catalyst for Total Carbon Utilization of C2 and C3 Biomass-Based Platform Molecules in the N-Formylation of Amines,Chem. Eur. J.,2021,27,16889 (Cover Picture).
10. Xingchao Dai and Feng Shi*. Green synthesis of N-alkyl-amines and amides via the building and transformation of carbonyl-containing molecules,Curr. Opin. Green Sustain. Chem.,2020,22,1.
11. Xingchao Dai,Sven Adomeit,Jabor Rabeah,Carsten Kreyenshulte,Angelika Brückner*,Hongli Wang and Feng Shi*. Sustainable co-synthesis of glycolic acid,formamides and formates from 1,3-dihydroxyacetone by a Cu/Al2O3 catalyst with single active sites,Angew. Chem. Int. Ed.,2019,58,5251 (Inside Back Cover).
12. Xingchao Dai,Bin Wang,Aiqin Wang and Feng Shi*. Amine formylation with CO2 and H2 catalyzed by heterogeneous Pd/PAL catalyst,Chinese J. Catal.,2019,40,1141.
13. Xingchao Dai and Feng Shi*. N-alkyl amides synthesis via N-alkylation of amides with alcohols,Org. Biomol. Chem.,2019,17,2044.
14. Xingchao Dai,Hangkong Yuan,Yongji Huang,Hongli Wang,Yajuan Wu,Yujing Zhang,Shujuan Liu,Feng Shi*. Catalyst systems for the clean synthesis of nitrogen-containing fine chemicals based on the building and transformation of carbonyl-containing molecules,Sci. Sin. Chim.,2018,48,1568.
15. Xingchao Dai,Jabor Rabeah,Hangkong Yuan,Angelika Bruckner*,Xinjiang Cui,and Feng Shi*. Glycerol as a Building Block for Prochiral Aminoketone,N-Formamide,and N-Methyl Amine Synthesis,ChemSusChem 2016,9,3133 (VIP).
16. Xingchao Dai,Xinjiang Cui,Hangkong Yuan,Youquan Deng and Feng Shi*. Cooperative transformation of nitroarenes and biomass-based alcohols catalyzed by CuNiAlOx. RSC Adv.,2015,5,7970.
17. Xingchao Dai,Xinjiang Cui,Youquan Deng and Feng Shi*. A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions,RSC Adv.,2015,5,43589.
18. Prakash Kumar Sahoo,Rakesh Maiti,Peng Ren,Juan José Delgado Jaén,Xingchao Dai,Giovanni Barcaro,Susanna Monti,Alina Skorynina,Anna Rokicinśka,Aleksander Jaworski,Laura Simonelli,Piotr Kust́rowski,Jabor Rabeah,and Shoubhik Das*. An Atomically Dispersed Mn Photocatalyst for Vicinal Dichlorination of Nonactivated Alkenes,J. Am. Chem. Soc.,2025,147,14,11829.
19. Suman Pradhan,Jun Hu,Peng Ren,Yuman Qin,Noopur Jain,Susanna Monti, Giovanni Barcaro,Aleksander Jaworski,Xingchao Dai,Jabor Rabeah,Joaquin Silvestre-Albero,Veronica Celorrio,Anna Rokicinnska,Piotr Kusstrowski,Sandra Van Aert,Sara Bals,Shoubhik Das*. An Atomically Dispersed Photocatalyst for Undirected para-Selective C–H bond Functionalizations,Angew. Chem. Int. Ed.,2025,64,e202508512.
20. Yong Peng,Nils Rockstroh,Jabor Rabeah,Stephan Bartling,Xingchao Dai,Xuetao Qin,Trang Minh Pham,Annette-Enrica Surkus,Robert Thomas,Hermann Seitz,Henrik Junge* & Matthias Beller*. Photocatalytic synthesis of ethylene glycol and hydrogen from methyl tert-butyl ether,Nat. Commun.,2025,16,3959.
21. Guomin Li,Bin Wang,Xingchao Dai,Feng Shi,Yong Ding and Xinjiang Cui*. Co-catalysis of propane dehydrogenation by Al2O3-supported Ni nanoparticles and VOx,Catal. Sci. Technol.,2025,15,318.
22. Liping Zhang,Xingchao Dai,Teng Li,Ce Liu,Bin Wang,Guomin Li,Peiqing Zhao and Xinjiang Cui*. Pd single-atom decorated OMS-2 nanorod for efficient silane oxidation,New J. Chem.,2024,48,9333.
23. Rakesh Maiti,Jeet Chakraborty,Prakash Kumar Sahoo,Ipsita Nath,Xingchao Dai,Jabor Rabeah,Nathalie De Geyter,Rino Morent,Pascal Van Der Voort and Shoubhik Das*. A Covalent Triazine Framework for Photocatalytic AntiMarkovnikov Hydrofunctionalizations,Angew. Chem. Int. Ed., 2024,63,e202415624.
24. Ce Liu,Teng Li,Xingchao Dai,Jian Zhao,Liping Zhang,Xinjiang Cui. Mechanism regulation over dual-atom catalyst enables high-performance oxidative alcohol esterification,Sci. Bull.,2025,70,78.
25. Junhao Huang,Marcus Klahn,Xinxin Tian,Xingchao Dai,Jabor Rabeah,Victoria Aladin,Björn Corzilius,Stephan Bartling,Henrik Lund,Norbert Steinfeldt,Tim Peppel,Andrew J. Logsdail,Haijun Jiao and Jennifer Strunk. Exfoliated Polymeric Carbon Nitride Nanosheets for Photocatalytic Applications,ACS Appl. Nano Mater.,2024,7,7442.
26. Shujuan Liu,Teng Li,Feng Shi,Haiying Ma,Bin Wang,Xingchao Dai,and Xinjiang Cui. Constructing multiple active sites in iron oxide catalysts for improving carbonylation reactions,Nat. Commun.,2023,14,4973.
27. Dongcheng He,Teng Li,Xingchao Dai,Shujuan Liu,Xinjiang Cui and Feng Shi. Construction of Highly Active and Selective Molecular Imprinting Catalyst for Hydrogenation,J. Am. Chem. Soc.,2023,145,20813.
28. Ce Liu,Teng Li,Xingchao Dai,Jian Zhao,Dongcheng He,Guomin Li,Bin Wang,and Xinjiang Cui. Catalytic Activity Enhancement on Alcohol Dehydrogenation via Directing Reaction Pathways from Single- to Double-Atom Catalysis,J. Am. Chem. Soc.,2022,144,4913.
29. Kang Zhao,Hongli Wang,Xinzhi Wang,Teng Li,Xingchao Dai,Liping Zhang,Xinjiang Cui,Feng Shi. Confinement of atomically dispersed Rh catalysts within porous monophosphine polymers for regioselective hydroformylation of alkenes. J. Catal.,2021,401,321.
30. Dongcheng He,Tao Wang,Teng Li,Xinzhi Wang,Hongli Wang,Xingchao Dai,Feng Shi. Efficient hydrogenation catalyst designing via preferential adsorption sites construction towards active copper,J. Catal.,2021,400,397.
31. Shujuan Liu,Xingchao Dai,Hongli Wang,Xinzhi Wang,and Feng Shi. Organic Ligand-Free Hydroformylation with Rh Particles as Catalyst,Chin. J. Chem.,2019,37,139.
32. Yajuan Wu,Tao Wang,Hongli Wang,Xinzhi Wang,Xingchao Dai & Feng Shi. Active catalyst construction for CO2 recycling via catalytic synthesis of N-doped carbon on supported Cu,Nat. Commun.,2019,10,2599.
33. Yajuan Wu,Yongji Huang,Xingchao Dai,and Feng Shi. Alcohol Amination Catalyzed by Copper Powder as a Self-Supported Catalyst,ChemSusChem,2019,12,3185.
34. Ruiping Wei,Xingchao Dai and Feng Shi. Enhanced CO2 Adsorption on Nitrogen-Doped Carbon Materials by Salt and Base Co-Activation Method,Materials, 2019,12,1207.
35. Hongli Wang,Yongji Huang,Qi Jiang,Xingchao Dai and Feng Shi. Reductive N-methylation of quinolines with paraformaldehyde and H2 for sustainable synthesis of N-methyl tetrahydroquinolines,Chem. Commun.,2019,55,3915.
36. Shujuan Liu,Xingchao Dai,Hongli Wang and Feng Shi. Organic ligand and solvent free oxidative carbonylation of amine over Pd/TiO2 with unprecedented activity,Green Chem.,2019,21,4040.
37. Xinjiang Cui,Xingchao Dai,Annette-Enrica Surkus,Kathrin Junge,Carsten Kreyenschulte,Giovanni Agostini,Nils Rockstroh,Matthias Beller. Zinc single atoms on N-doped carbon: An efficient and stable catalyst for CO2 fixation and conversion,Chinese J. Catal.,2019,40,1679.
38. Yujing Zhang,Shaofeng Pang,Zhihong Wei,Haijun Jiao,Xingchao Dai,Hongli Wang and Feng Shi. Synthesis of a molecularly defined single-active site heterogeneous catalyst for selective oxidation of N-heterocycles. Nat. Commun.,2018,9,1465.
39. Yujing Zhang,Xingchao Dai,Hongli Wang,Feng Shi. Catalytic Synthesis of Formamides with Carbon Dioxide and Amines. Acta Phys. -Chim. Sin.,2018,34,845.
40. Hongli Wang,Hangkong Yuan,Benqun Yang,Xingchao Dai,Shan Xu,and Feng Shi. Highly Selective N‑Monomethylanilines Synthesis From Nitroarene and Formaldehyde via Kinetically Excluding of the Thermodynamically Favorable N,N-Dimethylation Reaction,ACS Catal.,2018,8,3943.
41. Shujuan Liu,Hongli Wang,Xingchao Dai and Feng Shi. Organic ligand-free carbonylation reactions with unsupported bulk Pd as catalyst,Green Chem.,2018,20,3457.
42. Hongli Wang,Yongji Huang,Xingchao Dai and Feng Shi. N-Monomethylation of amines using paraformaldehyde and H2,Chem. Commun.,2017,53,5542.
43. Xinjiang Cui,Kathrin Junge,Xingchao Dai,Carsten Kreyenschulte,Marga-Martina Pohl,Sebastian Wohlrab,Feng Shi,Angelika Brückner and Matthias Beller. Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions,ACS Cent. Sci.,2017,3,580.
44. Huimin Yang,Xinjiang Cui,Xingchao Dai,Youquan Deng and Feng Shi. Carbon-catalysed reductive hydrogen atom transfer reactions,Nat. Commun.,2015,6,6478.
45. Xinjiang Cui,Xingchao Dai,Yan Zhang,Youquan Deng and Feng Shi. Methylation of amines,nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen,Chem. Sci.,2014,5,649.
46. Xinjiang Cui,Xingchao Dai,Youquan Deng,and Feng Shi. Development of a General Non-Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia,Chem. Eur. J.,2013,19,3665.
● 专著：
1. Feng Shi,Hongli Wang and Xingchao Dai,Carbonyl Compounds: Reactants,Catalysts and Products,2021
2. Xingchao Dai,Catalytic amination for N-alkyl amine synthesis: (Chapter 1) N-alkyl amine synthesis by catalytic alcohol amination,2018
3. Xingchao Dai and Xinjiang Cui,Catalytic amination for N-alkyl amine synthesis: (Chapter 2) N-alkyl amines synthesis by catalytic coupling of amines,2018
4. Hongli Wang and Xingchao Dai,Catalytic amination for N-alkyl amine synthesis: (Chapter 4) N-Alkyl Amines Synthesis by Hydroaminomethylation,2018
5. Xingchao Dai and Feng Shi,Science of synthesis: Catalytic reduction in organic synthesis,2018,1,127.
● 专利：
1.石峰，代兴超，黄永吉；一种羟基乙酸的制备方法,中国专利，申请号：201810124257.6
2.石峰，代兴超，袁航空；一种N-甲酰化胺类化合物的制备方法，中国专利，申请号：201810369675.1
3. 石峰，魏瑞平，代兴超，王红利；一种甲酸酯类化合物的制备方法，中国专利，申请号：201810124892.
社会任职：
个人网页：
